pe
pep-10605 v1 CC-BY-SA-4.0

Kisspeptin-54 (27-54): reproductive hormone fragment (human)

A lab-made fragment of a natural hormone that triggers the brain's signal chain for sex-hormone production and fertility; experimental, not yet an approved drug.

statussynthesized targetKISS1R length28 aa refs11
status 4 / 5
prediction metrics boltz-2 2.2.1
ipTM0.750
pTM0.806
avg pLDDT66.3
ranking score0.680
STRUCTURE · PEP-10605 × KISS1R
ranking0.680
target interface 4.5Å peptide drag rotate · ctrl+scroll zoom · right-click pan
boltz-2 2.2.1 · mmCIF ↓ download
sequence28 aa
151015202528
IPAPQGAVLVQREK DLPNYNWNSFGLRF
overview readme

What this is

Kisspeptin-54 (27-54) is a 28-residue synthetic fragment spanning positions 27 through 54 of the full-length human kisspeptin-54 peptide — the C-terminal half of the 54-amino-acid form that is the dominant circulating kisspeptin isoform in adult humans. Like all biologically active kisspeptins, it acts on the kisspeptin receptor (KISS1R, formerly called GPR54), a G protein-coupled receptor concentrated on GnRH neurons in the hypothalamus. Because kisspeptin signals sit at the top of the chain that drives sex-hormone production, the kisspeptin family has attracted intense clinical interest for fertility treatment, reproductive hormone disorders, and diagnostic testing of puberty-related conditions. The raw sequence IPAPQGAVLVQREKDLPNYNWNSFGLRF (28 aa) encodes the peptide backbone faithfully, but in the endogenous context the C-terminus carries an amide cap (–NH₂) that is not represented in the stored one-letter sequence.

This fragment is distinct from the two better-characterised clinical forms: full-length kisspeptin-54 (used in IVF and HSDD trials) and kisspeptin-10 (the C-terminal decapeptide, which contains the core binding motif). As a mid-length fragment, its receptor-binding potency is intermediate to weaker: it retains the KISS1R-binding C-terminal motif but lacks portions of the N-terminal extension that contribute to the higher potency of kisspeptin-54.


History

The story of this fragment begins with its parent gene, KISS1, discovered in 1996 as a metastasis-suppressor in melanoma cells at Hershey Medical Center, Pennsylvania — named informally after the town's signature Hershey's Kisses candy. The reproductive role of kisspeptin was established in 2003 when independent groups identified that loss-of-function mutations in KISS1R (GPR54) cause idiopathic hypogonadotropic hypogonadism in humans, positioning the receptor — and its endogenous ligands — as master regulators of reproductive hormone release (Mead and colleagues, 2007).

The KISS1 gene encodes a 145-amino-acid precursor (prepro-kisspeptin-1) that is proteolytically processed to yield kisspeptin-54 as the predominant full-length circulating form, along with shorter isoforms including kisspeptin-14, kisspeptin-13, and kisspeptin-10. The (27-54) fragment catalogued here represents a synthetic sub-fragment of kisspeptin-54 — spanning its C-terminal half — used in research to probe receptor pharmacology and structure–activity relationships within the kisspeptin system.

The kisspeptin receptor (KISS1R/GPR54) was formally named and characterised in the IUPHAR nomenclature framework (Kirby and colleagues, 2010), establishing the framework within which fragments like this one are evaluated.


What it does

All active kisspeptins — including this (27-54) fragment — bind KISS1R on hypothalamic GnRH neurons, triggering GnRH pulse generation. This in turn drives pituitary release of LH and FSH, the gonadotropins that signal the gonads to produce testosterone and estrogen. The kisspeptin system sits at the very top of the reproductive hormone axis (Xie and colleagues, 2022).

The (27-54) fragment contains the conserved C-terminal region that is necessary for KISS1R binding and activation, but its binding potency relative to full-length kisspeptin-54 or the minimal active kisspeptin-10 decapeptide has not been established in published human pharmacology studies available in this dossier. Structure–activity work across the kisspeptin family shows that the C-terminal Arg-Phe (RF) motif is the minimal binding determinant, and that longer C-terminal extensions generally retain activity, while N-terminal extensions of varying length modulate potency and duration of action (Kirby and colleagues, 2010).

Human clinical pharmacology has been most extensively characterised for kisspeptin-54 (full-length) and kisspeptin-10. Dhillo and colleagues (2007) demonstrated that kisspeptin-54 stimulates gonadotropin release in women most potently during the preovulatory phase of the menstrual cycle, establishing phase-dependent sensitivity of the KISS1R axis. George and colleagues (2011) showed that kisspeptin-10 potently stimulates LH and increases LH pulse frequency in men. The (27-54) fragment occupies the pharmacological middle ground between these two well-studied forms but lacks dedicated published human pharmacology studies to date.

Beyond reproduction, kisspeptin signalling has been implicated in metabolic regulation — circulating kisspeptin levels associate with insulin resistance and glucose homeostasis in human observational studies — and emerging evidence from brain-imaging trials suggests effects on sexual and emotional neural processing (Izzi-Engbeaya and colleagues, 2019).


Evidence

  • Human: Published clinical pharmacology for this specific (27-54) fragment is not established in the primary literature indexed to this card. Clinical evidence for the broader kisspeptin-54 class includes multiple RCTs on IVF oocyte maturation triggering, hypothalamic amenorrhea, and hypoactive sexual desire disorder, all conducted with full-length kisspeptin-54 or kisspeptin-10 — not with this fragment specifically.
  • Animal: The (27-54) sequence is present in species-comparative sequence alignments of kisspeptin across mammals, including goat, sheep, and cattle (Okamura and colleagues, 2013). Cross-species conservation of the C-terminal region confirms the functional importance of this segment, but fragment-specific animal pharmacology is not documented in the dossier refs.
  • In vitro: Receptor pharmacology characterised at KISS1R, a class A GPCR, via G protein-coupled signalling assays — the (27-54) fragment retains the C-terminal binding motif described in KISS1R nomenclature reviews (Kirby and colleagues, 2010).

Known effects

  • GnRH pulse stimulation — Mechanistic (class-level); the C-terminal KISS1R-binding motif is present in this fragment. Human evidence at the fragment level is not established.
  • LH and FSH release — Established for kisspeptin-54 and kisspeptin-10 (Dhillo and colleagues, 2007; George and colleagues, 2011); extrapolated to this fragment by class mechanism, not directly demonstrated.
  • Cross-species conservation of reproductive signalling — Preclinical; the kisspeptin system controls the HPG axis in all vertebrates studied (Tsutsui and colleagues, 2010; Akazome and colleagues, 2010).

Safety signals

No published clinical safety data exist specifically for this fragment. Safety characterisation of the kisspeptin-54 class in humans comes from trials using the full 54-residue peptide; the (27-54) fragment has not been studied in registered clinical trials and carries no independent safety record in the accessible literature.

The class-level signals from kisspeptin-54 trials include: injection-site reactions (the most commonly reported adverse event in subcutaneous trials), absence of documented serious adverse events in short-duration trial exposures, and a theoretical concern around tachyphylaxis — receptor desensitisation observed with continuous administration that limits sustained hormonal effects (Mead and colleagues, 2007).


Regulatory status

  • US: Not FDA-approved for any indication. No IND-level clinical development appears to be registered for this specific fragment.
  • EU/UK: Not authorised by EMA or MHRA. The broader kisspeptin-54 class has been investigated in UK clinical trials (primarily Imperial College London's group) without proceeding to marketing authorisation.
  • WADA: Falls under S2 (peptide hormones, growth factors, and related substances) by mechanism — any peptide that stimulates endogenous LH and gonadotropin release is prohibited in competitive sport at all times. Athletes should avoid.

Mechanism

KISS1R (formerly GPR54, also denoted AXOR12 or hOT7T175 in older literature) is a class A GPCR expressed on GnRH neurons in the hypothalamic arcuate nucleus and anteroventral periventricular nucleus (Kirby and colleagues, 2010). Kisspeptin binding activates Gαq/11-coupled phospholipase C signalling, producing IP₃ and DAG, raising intracellular calcium, and triggering GnRH secretion into the pituitary portal circulation. This GnRH pulse activates gonadotroph cells to release LH and FSH, which in turn stimulate gonadal steroidogenesis.

The (27-54) fragment spans the region from position 27 of kisspeptin-54, which lies in the mid-peptide segment connecting the less-conserved N-terminal extension to the conserved C-terminal binding core. The C-terminal Arg-Phe-NH₂ motif — shared with all active kisspeptin isoforms — is the minimal pharmacophore required for KISS1R engagement (Kirby and colleagues, 2010). Rønnekleiv and colleagues (2013) reviewed the electrophysiological mechanisms by which kisspeptin activates GnRH neurons, including membrane depolarisation via closure of GIRK channels and opening of TRPC channels.

Kisspeptin neurons in the arcuate nucleus co-express neurokinin B (NKB) and dynorphin — the so-called KNDy neuron population — which generates the self-sustaining oscillatory drive underlying pulsatile GnRH release (Xie and colleagues, 2022). The (27-54) fragment acts downstream of this oscillatory system as an exogenous KISS1R agonist that can engage the same receptor pathway without reproducing the endogenous NKB-driven pulse architecture.

Idiopathic hypogonadotropic hypogonadism caused by loss-of-function mutations in KISS1R (GPR54) confirms that intact kisspeptin signalling is non-redundant for human reproductive competence (Bonomi and colleagues, 2012; Mead and colleagues, 2007).


Open questions

  • Fragment-specific binding affinity and functional potency at KISS1R relative to kisspeptin-54 and kisspeptin-10 have not been published in accessible primary literature.
  • Whether the (27-54) fragment offers any pharmacokinetic advantages (altered plasma half-life, modified receptor on-rate/off-rate) compared to the full-length or decapeptide forms remains uncharacterised.
  • The biological significance of the N-terminal extension (residues 27-44 of KP-54) beyond serving as a spacer from the binding core is not established.
  • Tachyphylaxis kinetics for this specific fragment at KISS1R have not been studied.
  • No oral or intranasal formulation data exist for this fragment (intranasal delivery has been validated only for full-length kisspeptin-54 in human trials).

Related peptides

  • Kisspeptin-10 — the C-terminal decapeptide (residues 45-54 of kisspeptin-54) containing the minimal KISS1R-binding pharmacophore; the most widely used research form and studied in men for LH pulse stimulation (George and colleagues, 2011).
  • Full-length kisspeptin-54 — the parent 54-residue peptide from which this fragment is derived; used in IVF oocyte maturation trigger trials and HSDD clinical research (Dhillo and colleagues, 2007).
Hypotheses2 directions▾ collapse

Research directions for this peptide, selected from the current sources — hypotheses you can explore and model. None of it is proven yet; tap any one to see the full thinking.

openupdated 2026-06-11

Does the proline pair at the start of this fragment prevent the middle section from folding, leaving it as a flexible tail attached to the active tip?

If confirmed, drug designers could strip away the disordered middle and build a shorter, cheaper peptide that works as well as the longer hormone for treating fertility problems.

The hypothesis
The N-terminal proline-rich motif (IPAP, residues 1-4) of the 27-54 fragment imposes a rigid turn that prevents the mid-region (residues 5-18) from forming any stable helical secondary structure, making the fragment a largely disordered tether that presents the KISS1R-binding C-terminal octapeptide in a partially constrained orientation distinct from both kisspeptin-10 and full kisspeptin-54.
Why it’s plausible
The sequence opens with IPAPQ: two prolines at positions 2 and 4 are canonical helix-breakers and beta-turn inducers. The pLDDT of 66.3 corroborates low structural order across most of the chain. Kisspeptin-10 (the C-terminal decapeptide YNWNSFGLRF) is the minimal active unit; the mid-region of this fragment may not contribute positive contacts but may instead sterically modulate receptor approach angle relative to the free decapeptide.
Why it matters
If the IPAP motif functionally decouples the mid-region from the binding epitope, it explains the intermediate potency of this fragment and could guide truncation or stapling strategies that preserve or exceed kisspeptin-54 potency without the full 54-residue length.
Plausibility.70
Novelty.45
Impact.55
Basis · grounding1 paper · 2 computed/notes
[1]
sequenceSequence IPAPQGAVLVQREKDLPNYNWNSFGLRF has Pro at positions 2 and 4, classic beta-turn/helix-breaking positions
[2]
structurepLDDT=66.3 indicates globally moderate-to-low structural confidence, consistent with intrinsic disorder in the N/mid-region
[3]
paper
KISS1R pharmacology review establishes that the C-terminal core motif drives receptor activation
doi: 10.1124/pr.110.002774
openupdated 2026-06-11

If the loose, flexible middle of this fragment were replaced with a rigid but neutral connector, would the resulting molecule activate the kisspeptin receptor more strongly?

A more potent kisspeptin fragment could reduce doses needed for fertility treatments like IVF, potentially cutting costs and side effects for patients undergoing hormone stimulation therapy.

The hypothesis
Replacing the flexible mid-region (residues 5-18, sequence GAVLVQREKDLPNY) with a rigid glycine-serine linker of matched length would generate a synthetic kisspeptin analog with higher receptor-binding potency than this fragment and comparable to kisspeptin-54, because the flexible mid-region currently acts as an entropic penalty that is paid on binding without contributing direct receptor contacts.
Why it’s plausible
Intermediate potency of this 27-54 fragment relative to both kisspeptin-10 and kisspeptin-54 has been noted in the readme. Kisspeptin-54's N-terminal extension (residues 1-26) likely makes stabilizing contacts not present in this fragment. The mid-region GAVLVQREKDLPNY contributes no known receptor pharmacophore. A GS-linker would reduce conformational entropy of the unbound state, lowering the entropic cost of adopting the bound conformation and potentially increasing apparent affinity.
Why it matters
A synthetic kisspeptin analog with improved potency and defined structure would be a cleaner pharmacological tool and could reduce the dose needed for clinical fertility induction, an outcome with direct relevance to IVF and hypogonadotropic hypogonadism therapy.
Plausibility.60
Novelty.55
Impact.55
Basis · grounding3 computed/notes
[1]
noteReadme states this fragment has intermediate-to-weaker potency compared to both kisspeptin-10 and full kisspeptin-54, implicating the mid-region as a non-contributing entropic burden
[2]
sequenceMid-region GAVLVQREKDLPNY (residues 5-18) contains no known KISS1R pharmacophore residues; C-terminal WNSFGLRF is the minimal binding motif
[3]
structurepLDDT=66.3 globally and moderate ipTM=0.75 suggest the mid-region is disordered in the complex, consistent with it being an entropic burden rather than a contact contributor
details expand to inspect
full evidence table2 metrics
metricvaluetool
ipTM 0.7503631711006165 boltz-2
ranking score 0.680412232875824 boltz-2
3-letter notation
Ile-Pro-Ala-Pro-Gln-Gly-Ala-Val-Leu-Val-Gln-Arg-Glu-Lys-Asp-Leu-Pro-Asn-Tyr-Asn-Trp-Asn-Ser-Phe-Gly-Leu-Arg-Phe
recipeboltz-2 2.2.1
parametervalue
modelboltz-2 2.2.1
weights
hardwarevast_v100_32gb
mlx version
python
random seed1
msa strategycolabfold_local
runtime
predicted by
predicted at2026-05-22
citationbibtex
peptidemodel (2026). Kisspeptin-54 (27-54): reproductive hormone fragment (human) (pep-10605, v1). PeptideModel. https://peptidemodel.com/card/pep-10605
@peptide{pep10605,
  sequence = {IPAPQGAVLVQREKDLPNYNWNSFGLRF},
  target   = {kiss1r},
  author   = {peptidemodel},
  year     = {2026},
  status   = {synthesized}
}
related peptides 5 by signal overlap
clinical trials 10 on ct.gov · checked 2026-05-22
ct.gov trials 10
with results 3
PubMed reviews 2
by phase
6phase 15phase 2
by status
7completed1recruiting2terminated
references 11 papers
[2]
Kisspeptin Excitation of GnRH Neurons
Rønnekleiv, O. et al. Advances in Experimental Medicine and Biology 2013
supporting
[7]
Kisspeptin and Glucose Homeostasis
Izzi-Engbeaya, C. et al. Seminars in Reproductive Medicine 2019
supporting
[8]
Kisspeptin-10 Is a Potent Stimulator of LH and Increases Pulse Frequency in Men
George, J. et al. The Journal of Clinical Endocrinology & Metabolism 2011
supporting
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