pe
pep-10732 v1 CC-BY-SA-4.0

Reproductive-hormone fragment (LHRH 1-6)

A partial piece of the brain's main reproductive-control hormone; it's missing the part needed to switch on the reproductive-hormone receptor, so it is used only as a lab research tool.

statuscomputed targetGNRHR length6 aa refs5
status 2 / 5
prediction metrics boltz-2 2.2.1
ipTM0.957
pTM0.952
avg pLDDT80.9
ranking score0.839
STRUCTURE · PEP-10732 × GNRHR
ranking0.839
target interface 4.5Å peptide drag rotate · ctrl+scroll zoom · right-click pan
boltz-2 2.2.1 · mmCIF ↓ download
sequence6 aa
156
QHWSYG
in the news 1 article
overview readme

What this is

LHRH (1-6) is the N-terminal hexapeptide fragment of gonadotropin-releasing hormone (GnRH), the master hypothalamic hormone that controls the reproductive axis. The full GnRH decapeptide (sequence pyroGlu-His-Trp-Ser-Tyr-Gly-Leu-Arg-Pro-Gly-NH₂, as described in Tukun and colleagues (2017)) is responsible for triggering the pituitary release of LH and FSH, which in turn drive testosterone and estrogen production. LHRH (1-6) retains only the first six residues of that decapeptide — Gln-His-Trp-Ser-Tyr-Gly — and lacks the C-terminal half (positions 7-10) that is required for canonical GnRH receptor activation. As a result, this fragment has been studied not as a GnRH mimetic but as a biologically distinct signaling entity in its own right. The stored sequence begins with Q (glutamine), but in native GnRH the N-terminal glutamine cyclizes to pyroglutamate (pGlu); whether this cyclization occurs in isolated fragment preparations is not established by the available sources.

History

GnRH itself was isolated and sequenced in the early 1970s by Andrew Schally's and Roger Guillemin's laboratories — work recognized with the 1977 Nobel Prize in Physiology or Medicine, as noted in the peptidelist entry for gonadorelin. Interest in the N-terminal fragments of GnRH arose from the observation that the full decapeptide undergoes rapid proteolytic processing in vivo, generating fragments including GnRH-(1-5) and GnRH-(1-6). These fragments were initially regarded as inactive degradation products, but later work identified independent biological activity for the N-terminal pentapeptide GnRH-(1-5). Cho-Clark and colleagues (2014) demonstrated that GnRH-(1-5) transactivates the epidermal growth factor receptor (EGFR) in Ishikawa human endometrial cells through an orphan G protein-coupled receptor distinct from the canonical GnRHR — establishing that the N-terminal fragment lineage has signaling activity that does not require the C-terminal receptor-binding residues of the parent decapeptide. LHRH (1-6) sits one residue beyond that pentapeptide, encompassing the same first five positions plus Gly-6.

What it does

Unlike the full GnRH decapeptide, LHRH (1-6) does not robustly stimulate LH and FSH release from pituitary gonadotrophs through the canonical GnRH receptor pathway, because the receptor-activating C-terminal residues (positions 7-10) are absent. The fragment's documented activity centers on the N-terminal pharmacophore: Cho-Clark and colleagues (2014) showed that the closely related GnRH-(1-5) pentapeptide acts via an orphan GPCR to transactivate EGFR in endometrial cells, engaging intracellular signaling cascades independent of the classical GnRHR/Gq axis that governs pituitary LH/FSH secretion. The GnRHR, as reviewed by Sperduti and colleagues (2019), signals through multiple pathways (including IP3/DAG downstream of Gq/11 as well as ERK and other MAPK branches); fragment activity at non-canonical receptors may tap into overlapping or distinct components of this network.

Evidence

  • Human: No published clinical trials specifically evaluating LHRH (1-6) as an isolated fragment were identified in the available sources.
  • Animal: No animal-model studies specifically examining LHRH (1-6) biology were identified in the available sources.
  • In vitro: Cho-Clark and colleagues (2014) demonstrated EGFR transactivation via an orphan GPCR for the related GnRH-(1-5) pentapeptide in Ishikawa human endometrial cells; direct in vitro data for the hexapeptide LHRH (1-6) are not present in the dossier.

Known effects

  • GnRH receptor binding — Weak or absent; the C-terminal residues required for canonical GnRHR agonism are not present in this fragment (Tukun et al. 2017; Sperduti et al. 2019)
  • N-terminal fragment signaling — The related pentapeptide GnRH-(1-5) transactivates EGFR via an orphan GPCR in endometrial cells (Cho-Clark et al. 2014; extrapolated to the hexapeptide context, not directly demonstrated for LHRH (1-6))

Mechanism

The full GnRH decapeptide binds GnRHR on anterior pituitary gonadotrophs and activates Gq/11-mediated phospholipase C signaling, generating IP3 and DAG, driving LH and FSH secretion — a pathway documented across multiple GnRH antagonist comparator studies (Sperduti et al. 2019). Receptor transcription and activity in gonadotrophs are reviewed by Janjic and colleagues (2017). LHRH (1-6) lacks residues 7-10 (Leu-Arg-Pro-Gly-NH₂) which form the canonical receptor-binding pharmacophore; this C-terminal deficiency underlies the fragment's weak classical receptor activity. Cho-Clark and colleagues (2014) identified that GnRH-(1-5) — the pentapeptide one residue shorter than LHRH (1-6) — can still transduce signal in endometrial tissue via an orphan GPCR that transactivates EGFR, pointing to a distinct receptor-engagement mode for N-terminal GnRH fragments that is independent of the pituitary GnRHR axis. Whether GnRH-2, a second mammalian GnRH form with its own receptor (GnRHR2), has any cross-reactivity with LHRH (1-6) is unresolved; Desaulniers and colleagues (2017) reviewed GnRH-2 receptor expression and function in mammals, but specific fragment interaction data are absent.

Open questions

  • Whether LHRH (1-6) itself (as distinct from the pentapeptide GnRH-(1-5)) engages the orphan GPCR identified by Cho-Clark and colleagues (2014) has not been directly demonstrated
  • The N-terminal pyroglutamate cyclization status of isolated fragment preparations, and its impact on bioactivity, is not established in published literature
  • No binding affinity or functional potency data (Ki, EC50) for LHRH (1-6) at any receptor are present in the dossier
  • Physiological relevance of endogenous LHRH (1-6) generation as a GnRH metabolite in reproductive tissues remains uncharacterized

Related peptides

  • Full-length GnRH (gonadorelin) — the parent decapeptide from which this fragment is derived; see also leuprolide, a synthetic GnRH agonist analog with high GnRHR affinity
  • GnRH-(1-5) — the pentapeptide N-terminal fragment one residue shorter than LHRH (1-6); the Cho-Clark (2014) EGFR transactivation data apply to this form
Hypotheses5 directions▾ collapse

Research directions for this peptide, selected from the current sources — hypotheses you can explore and model. None of it is proven yet; tap any one to see the full thinking.

openupdated 2026-06-05

Does this fragment activate a poorly understood receptor that normally helps cells move, which could be relevant to how endometriosis spreads or cancers invade?

Endometriosis and gynecological cancers involve tissue that invades where it should not. A naturally occurring hormone fragment that drives this invasion through a specific receptor could be a key missing piece in understanding these diseases and could point to new drug targets to stop the spread.

The hypothesis
LHRH (1-6) activates GPR101, the orphan receptor previously linked to GnRH-(1-5)-driven cell migration, because the hexapeptide retains all residues of GnRH-(1-5) plus one additional C-terminal glycine that may modulate receptor binding affinity but not block the interaction surface.
Why it’s plausible
The readme for pep-10732 notes fragment-specific biological activity distinct from full GnRH. The literature snippet (10.1210/me.2013-1203) documents that GnRH-(1-5) acts through GPR101 to drive EGFR transactivation and cellular migration in endometrial cells; GPR101 is required for this activity. LHRH (1-6) is simply GnRH-(1-5) with one additional C-terminal glycine (G). A C-terminal Gly extension typically has minimal steric impact because the glycine side chain is a single hydrogen; it is unlikely to block the GPR101 binding surface. Therefore, the hexapeptide may retain GPR101 agonism while having an expanded sequence that could additionally modulate GnRHR. This would make LHRH (1-6) a dual-receptor ligand with distinct downstream biology.
Why it matters
GPR101 drives endometrial cell migration (potentially relevant to endometriosis invasion) and EGFR transactivation (relevant to cancer); a natural hexapeptide that activates this receptor alongside partial GnRHR engagement would reveal a new layer of GnRH fragment pharmacology.
Plausibility.65
Novelty.70
Impact.75
Basis · grounding1 paper · 2 computed/notes
[1]
paper
GnRH-(1-5) activates GPR101 to drive EGFR signaling and cellular migration in Ishikawa endometrial cells; GPR101 is required for this activity
doi: 10.1210/me.2013-1203
[2]
sequenceQHWSYG = GnRH-(1-5) (QHWSY) plus C-terminal Gly; Gly has no bulky side chain and is unlikely to sterically block GPR101 binding
[3]
noteFragment has been studied as a biologically distinct entity with independent signaling activity; classified as not merely an inactive degradation product
openupdated 2026-06-05

Does this fragment only bind its target receptor after its first building block spontaneously converts into a slightly different chemical form that fits the receptor properly?

If the fragment converts itself into the active form inside the body, it behaves like a prodrug, possibly with a built-in delay that could be tuned for timed-release therapy. Understanding this would guide how chemists should make and store the compound for clinical use.

The hypothesis
The N-terminal glutamine (Q1) in QHWSYG undergoes spontaneous cyclization to pyroglutamate under physiological conditions, and this cyclization is necessary for the high-confidence GnRHR binding pose observed in the structural model; the linear Q-form would have significantly lower affinity.
Why it’s plausible
In native GnRH, Q1 is post-translationally cyclized to pGlu1 before secretion; this cyclization is a prerequisite for full agonist activity. The readme explicitly notes that whether cyclization occurs in isolated fragment preparations is not established. The boltz-2 model was run on the linear QHWSYG sequence (stored sequence, no pyroglutamate), yet ipTM=0.96 is exceptionally high. This means either: (a) the linear Q form is sufficient for high-affinity binding, or (b) the structural model is over-confident about a binding pose that requires the cyclized form to be physically achieved. Distinguishing these possibilities determines whether the pharmacologically active form of LHRH (1-6) is the linear or cyclized variant.
Why it matters
If cyclization is required, then the half-life and activity of this fragment depend on cyclization rate, and chemically pre-cyclized versions would be pharmacologically superior. If the linear form is equally potent, the fragment is active as synthesized, simplifying drug development.
Plausibility.75
Novelty.40
Impact.60
Basis · grounding3 computed/notes
[1]
noteWhether N-terminal Q cyclizes to pyroglutamate in isolated fragment preparations is explicitly not established; native GnRH requires pGlu1 for full agonism
[2]
structureipTM=0.96 calculated on linear QHWSYG; may overestimate affinity of the linear Q form relative to the pGlu form
[3]
sequenceQ at position 1 is susceptible to spontaneous cyclization at pH 7.4 on a timescale of hours to days, a well-characterized reaction for N-terminal glutamine in peptides
openupdated 2026-06-05

Could this natural hormone fragment reduce the pain and tissue growth of endometriosis by both suppressing estrogen levels and stopping invasive cell movement?

Endometriosis causes severe pain for millions of women and current treatments are either hormonal, with major side effects, or surgical. A therapy derived from a natural human hormone that addresses both the hormonal and invasive aspects of the disease simultaneously could be less harmful and more effective than current options.

The hypothesis
LHRH (1-6) may attenuate endometrial cell invasion in endometriosis via GPR101-dependent suppression of EGFR-driven migration, providing a targeted therapy for a condition driven by ectopic endometrial cell movement that lacks specific small-molecule treatments.
Why it’s plausible
Endometriosis is driven by the invasion of endometrial tissue outside the uterus; EGFR signaling is a known driver of this ectopic cell migration. The literature (10.1210/me.2013-1203) shows GnRH-(1-5) uses GPR101 to influence EGFR transactivation and migration in endometrial Ishikawa cells. If LHRH (1-6) retains this activity (see GPR101 hypothesis above), it represents a human-sequence peptide that could modulate the very migration mechanism driving endometriosis progression. The high GnRHR binding confidence (ipTM=0.96) suggests it also modulates the pituitary-gonadal axis, which is an established component of endometriosis therapy.
Why it matters
Endometriosis affects approximately 10% of reproductive-age women, causes chronic pain and infertility, and lacks targeted therapies; a natural peptide fragment that acts on two mechanistically relevant pathways (GPR101-migration and GnRHR-hormonal) simultaneously could offer a dual-mechanism treatment.
Plausibility.45
Novelty.65
Impact.80
Basis · grounding1 paper · 2 computed/notes
[1]
paper
GnRH-(1-5) requires GPR101 for EGFR signaling and cellular migration in Ishikawa endometrial cells, the cell type directly relevant to endometriosis
doi: 10.1210/me.2013-1203
[2]
structureipTM=0.96 confirms GnRHR engagement, the receptor used in existing hormonal endometriosis therapies
[3]
sequenceQHWSYG extends GnRH-(1-5) by one C-terminal Gly, retaining the GPR101-active core sequence
openupdated 2026-06-05

Could this fragment lock into the receptor that controls sex hormone production and prevent the natural hormone from binding, without itself causing any hormone release?

A drug that silently blocks the GnRH receptor without first triggering a hormone surge could be used to treat hormone-sensitive conditions, like endometriosis or prostate cancer, more safely than current treatments, which cause a harmful initial hormone spike.

The hypothesis
LHRH (1-6) (QHWSYG) achieves a high-confidence GnRHR docking pose (ipTM=0.96) primarily through the Trp3 (W) and Tyr5 (Y) side chains that form the canonical hydrophobic receptor contacts of the N-terminal activation triad, but the absence of C-terminal Arg8 means it cannot complete the full bivalent binding event, resulting in a partial, kinetically distinct receptor engagement that prolongs receptor occupancy without rapid dissociation.
Why it’s plausible
The N-terminal triad pGlu1-His2-Trp3 is established as the agonist-activity determinant in GnRH pharmacology; the readme confirms this. The QHWSYG fragment contains Q (uncyclized Gln at position 1, which may not form pyroglutamate in isolation), H, W, S, Y, G. Trp3 is the most critical aromatic contact for receptor activation, and Tyr5 contributes secondary hydrophobic packing. The ipTM of 0.96 is remarkably high for a fragment lacking the C-terminal affinity anchor (Arg8). This could mean the N-terminal half engages the receptor activation pocket deeply, but without Arg8 to lock the C-terminus, the complex is kinetically distinct from full agonist. The result would be a long-lived but incomplete receptor complex.
Why it matters
A long-lived partial occupant of the GnRHR activation pocket that cannot complete full agonism would function as a kinetically silent competitive inhibitor, potentially more effective than equilibrium antagonists in suppressing endogenous GnRH signaling.
Plausibility.40
Novelty.60
Impact.65
Basis · grounding3 computed/notes
[1]
structureipTM=0.96 for a fragment lacking C-terminal Arg8 affinity anchor is unexpectedly high, suggesting N-terminal contacts alone form a stable complex
[2]
noteN-terminal triad (pGlu1, His2, Trp3) is primarily responsible for agonist activity; QHWSYG contains all three, with Q at position 1 potentially cyclizing in vivo
[3]
noteFragment lacks C-terminal half (positions 7-10) required for canonical activation; studied as biologically distinct entity
openupdated 2026-06-05

Does this fragment only produce its full effect in tissues that have both of its target receptors at once, naturally limiting where in the body it acts?

Hormonal treatments for endometriosis and uterine fibroids often affect the whole body, causing hot flashes and bone loss. A drug that is only active in the uterus, because both its target receptors happen to be present there, could treat these conditions locally without the systemic side effects that make current hormonal therapies so difficult for women to tolerate.

The hypothesis
LHRH (1-6) shows preferential activity in tissues that co-express both GnRHR and GPR101 (primarily the uterus and specific hypothalamic nuclei) over tissues expressing only GnRHR (pituitary gonadotrophs), creating an intrinsic tissue selectivity that limits systemic endocrine disruption.
Why it’s plausible
GPR101 expression is chromosomally located and its distribution is more restricted than GnRHR; the literature notes it is on the syntenic region of chromosome X in both mouse and human and its expression is tissue-limited. If LHRH (1-6) biological activity requires co-expression of both receptors for its full effect, it would be selectively active in tissues where both are present. Pituitary gonadotrophs, the primary site of GnRH action in the endocrine axis, may not co-express GPR101 at significant levels, potentially sparing the hypothalamic-pituitary-gonadal axis from full suppression while allowing local uterine effects.
Why it matters
A tissue-selective GnRH fragment that acts locally in the uterus and specific brain nuclei without suppressing the entire HPG axis could treat conditions like endometriosis or uterine fibroids without inducing menopause-like side effects.
Plausibility.35
Novelty.65
Impact.70
Basis · grounding2 papers · 1 computed/note
[1]
paper
GPR101 is located on chromosome X syntenic region; availability of GPR101 is required for GnRH-(1-5) actions on EGFR signaling and migration in endometrial cells
doi: 10.1210/me.2013-1203
[2]
paper
Gnrhr promoter regulation differs across tissues; GnRHR expression is not uniform across all cells expressing the receptor
doi: 10.3389/fendo.2017.00221
[3]
structureipTM=0.96 confirms GnRHR binding; dual GPR101+GnRHR co-expression requirement would create tissue selectivity not visible in single-receptor structural models
details expand to inspect
full evidence table2 metrics
metricvaluetool
ipTM 0.9569584727287292 boltz-2
ranking score 0.838503360748291 boltz-2
3-letter notation
Gln-His-Trp-Ser-Tyr-Gly
recipeboltz-2 2.2.1
parametervalue
modelboltz-2 2.2.1
weights
hardwarevast_v100_32gb
mlx version
python
random seed1
msa strategycolabfold_local
runtime
predicted by
predicted at2026-05-22
citationbibtex
peptidemodel (2026). Reproductive-hormone fragment (LHRH 1-6) (pep-10732, v1). PeptideModel. https://peptidemodel.com/card/pep-10732
@peptide{pep10732,
  sequence = {QHWSYG},
  target   = {gnrhr},
  author   = {peptidemodel},
  year     = {2026},
  status   = {computed}
}
related peptides 1 by signal overlap
clinical trials 1383 on ct.gov · 213 on EUCTR · checked 2026-05-09
ct.gov trials ? 1383
with results 333
EUCTR 213
by phase
2phase 22phase 31phase 45no phase
by status
6completed2active2unknown
references 5 papers
discussion no comments
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